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A Brief Review on Key Role of Perovskite Oxides as Catalyst

Pinky Yadav, Sangeeta Yadav, Shalu Atri, Ravi Tomar

2021ChemistrySelect35 citationsDOI

Abstract

Abstract The research work conducted mainly on the reduction reaction of NO x , the oxidation reaction of CO, and hydrocarbons, electro‐catalysis of oxygen in alkaline medium, and photocatalytic water splitting has proved excellent catalytic behavior of perovskite oxides. [16–23] Although only a few reports published usages of the perovskite oxides as catalysts for the organic transformation such as catalytic hydrogenation, Ullmann, Sonogashira reactions, and Suzuki couplings. [24–26] Yoon et al. have prepared K 2 CO 3 based LaMn 1‐x Cu x O 3 perovskite oxide as a potential catalyst and discussed their mechanistic aspects in various reactions occurring at room temperature. [27] Recently, Wu and Ajayan group has demonstrated the relationship between stoichiometry and activity of pure and B‐site substituted layered perovskite oxide in the decomposition reaction of isopropanol by considering Sr 2 Sn 1‐x Ru x O 4 (0≤x≤1) as catalyst. [28] In this scenario, present work aims to summarize the contribution of perovskite oxides as catalyst in numerous organic syntheses and catalysis, photocatalysis, and electrocatalysis reactions.

Topics & Concepts

CatalysisPerovskite (structure)Sonogashira couplingOxideStoichiometryDecompositionChemistryInorganic chemistryPhotocatalysisElectrocatalystRedoxMaterials sciencePalladiumPhysical chemistryOrganic chemistryElectrochemistryElectrodeCatalytic Processes in Materials ScienceAdvanced Photocatalysis TechniquesCatalysis and Oxidation Reactions