Visible-light-induced cross-coupling of aryl iodides with hydrazones <i>via</i> an EDA-complex
Pan Pan, Shihan Liu, Yu Lan, Huiying Zeng, Chao‐Jun Li
Abstract
Visible-light-induced catalyst-free cross-coupling of aryl iodides with hydrazones via single-electron-transfer was reported. The mechanistic investigations showed that the association of hydrazone anion with aryl iodides formed an EDA complex.
Topics & Concepts
ArylHydrazoneChemistryPhotosensitizerPhotochemistryTrifluoromethylReagentElectron transferVisible spectrumHalideAcceptorExcited stateMedicinal chemistryOrganic chemistryMaterials sciencePhysicsOptoelectronicsNuclear physicsCondensed matter physicsAlkylRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods