Post-synthetic modification of bis-iron(<scp>iii</scp>)-μ-oxo-porphyrin prisms to enhance oxygen reduction electrocatalysis
Daoyang Zhang, Lauren E. Rosch, Matthew R. Crawley, Timothy R. Cook
Abstract
Bis-iron( iii )-μ-oxo-porphyrin prisms may be tuned via post-synthetic tethering. Tethered prisms show enhanced selectivity for the Oxygen Reduction Reaction (ORR) and maintain a cofacial geometry under homogeneous ORR conditions.
Topics & Concepts
ElectrocatalystPorphyrinOxygen reductionReduction (mathematics)Oxygen reduction reactionOxygenChemistryCombinatorial chemistryPhotochemistryOrganic chemistryElectrochemistryElectrodePhysical chemistryGeometryMathematicsElectrocatalysts for Energy ConversionPorphyrin and Phthalocyanine ChemistryElectrochemical Analysis and Applications