Rational design of carborane-based Cu<sub>2</sub>-paddle wheel coordination polymers for increased hydrolytic stability
Zhen Li, Duane Choquesillo‐Lazarte, Julio Fraile, Clara Viñas, Francesç Teixidor, José Giner Planas
Abstract
-paddle wheel polymer (1), obtained from a related more symmetrical carborane-based linker. Both 1 and 2 were used as efficient heterogeneous catalysts for a model aza-Michael reaction but only 2 can be reused several times without significant degradation in catalytic activity.
Topics & Concepts
LinkerHydrolysisPolymerCatalysisCarboranePaddleRational designDegradation (telecommunications)ChemistryHydrolytic degradationPolymer chemistryChemical stabilityCombinatorial chemistryMaterials scienceChemical engineeringStereochemistryOrganic chemistryNanotechnologyComposite materialComputer scienceEngineeringOperating systemTelecommunicationsBoron Compounds in ChemistryMetal-Organic Frameworks: Synthesis and ApplicationsBoron and Carbon Nanomaterials Research