Effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior of diazoacetates initiated by π-allylPd complexes
Hiroaki Shimomoto, Moemi Nakajima, Akihiro Watanabe, Hirokazu Murakami, Tomomichi Itoh, Eiji Ihara
Abstract
We have revealed that the quality of control of the polymerization was improved by adding some compounds and polymer tacticity was dependent on the structures of π-allyl ligands.
Topics & Concepts
TacticityPolymerizationLigand (biochemistry)Polymer chemistryPolymerChemistryOrganic chemistryReceptorBiochemistryCyclopropane Reaction MechanismsSynthetic Organic Chemistry MethodsOrganometallic Complex Synthesis and Catalysis