A Zn(<scp>ii</scp>)-functionalized COF as a recyclable catalyst for the sustainable synthesis of cyclic carbonates and cyclic carbamates from atmospheric CO<sub>2</sub>
Somnath Sarkar, Swarbhanu Ghosh, Sk. Manirul Islam
Abstract
. More intriguingly, the catalytic system could be recycled over five times without a noticeable loss of catalytic performance for both reactions. This study opens an avenue for the Zn(II) embedded COF as a promising platform for regulating regioselectivity.
Topics & Concepts
CatalysisChemistryCovalent bondHigh-resolution transmission electron microscopyX-ray photoelectron spectroscopyYield (engineering)Inductively coupled plasmaGreen chemistryChemical engineeringTransmission electron microscopyOrganic chemistryNanotechnologyReaction mechanismMaterials scienceMetallurgyEngineeringQuantum mechanicsPhysicsPlasmaCarbon dioxide utilization in catalysisCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and Applications