Visible-light-mediated Barbier allylation of aldehydes and ketones<i>via</i>dual titanium and photoredox catalysis
Fusheng Li, Yuqing Chen, Shuangjie Lin, Caizhe Shi, Xiyu Li, Yuchen Sun, Zhuowen Guo, Lei Shi
Abstract
This study reports a photocatalytic Barbier-type allylation of various aldehydes and ketones with allyl halides for the synthesis of homoallylic alcohols driven by dual titanium and photoredox catalysis.
Topics & Concepts
ChemistryPhotoredox catalysisCatalysisPhotocatalysisHalideTitaniumAldehydeOrganic chemistryPhotochemistryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions