A tryptophan-based copper(<scp>ii</scp>) coordination polymer: catalytic activity towards Suzuki–Miyaura cross-coupling reactions
Ahmad Husain, Pooja Rani, Kuldeep Kaur Nar, Amit Pratap Singh, Rakesh Kumar, K.K. Bhasin, Girijesh Kumar
Abstract
An unusual tryptophan coordination mode with copper( ii ) wherein l -tryp is coordinated through the carboxylate and amine groups. A heterogeneous catalyst for the Suzuki cross-coupling reaction with ∼98% yield under normal reaction conditions.
Topics & Concepts
CopperYield (engineering)ChemistryCatalysisCarboxylateTryptophanAmine gas treatingPolymer chemistryCoupling reactionCoupling (piping)Organic chemistryCombinatorial chemistryAmino acidMaterials scienceBiochemistryMetallurgyMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesPolyoxometalates: Synthesis and Applications