Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel(II) Complexes
Tomohiro Ogawa, Narayan Sinha, Björn Pfund, Alessandro Prescimone, Oliver S. Wenger
Abstract
complexes. Our study contributes to making first-row transition metal complexes with partially filled d-orbitals more amenable to applications in photophysics and photochemistry.
Topics & Concepts
ChemistryExcited stateLigand field theoryLigand (biochemistry)CrystallographyIntramolecular forcePhotochemistryDenticitySteric effectsIsocyanideComputational chemistryAtomic physicsStereochemistryCrystal structureReceptorBiochemistryPhysicsOrganic chemistryIonOrganic Light-Emitting Diodes ResearchRadical Photochemical ReactionsCO2 Reduction Techniques and Catalysts