Reverse Intersystem Crossing Dynamics in Vibronically Modulated Inverted Singlet–Triplet Gap System: A Wigner Phase Space Study
Pijush Karak, Pradipta Manna, Ambar Banerjee, Kenneth Ruud, Swapan Chakrabarti
Abstract
We inspect the origin of the inverted singlet-triplet gap (INVEST) and slow change in the reverse intersystem crossing (rISC) rate with temperature, as recently observed. A Wigner phase space study reveals that, though INVEST is found at equilibrium geometry, variation in the exchange interaction and the doubles-excitation for other geometries in the harmonic region leads to non-INVEST behavior. This highlights the importance of nuclear degrees of freedom for the INVEST phenomenon, and in this case, geometric puckering of the studied molecule determines INVEST and the associated rISC dynamics.
Topics & Concepts
Intersystem crossingSinglet statePhase spaceDynamics (music)Phase (matter)PhysicsSpace (punctuation)Atomic physicsQuantum mechanicsComputer scienceOperating systemAcousticsExcited stateStrong Light-Matter InteractionsNonlinear Dynamics and Pattern FormationOrganic Light-Emitting Diodes Research