Mizoroki–Heck type reactions and synthesis of 1,4-dicarbonyl compounds by heterogeneous organic semiconductor photocatalysis
Jagadish Khamrai, Saikat Das, Aleksandr Savateev, Markus Antonietti, Burkhard König
Abstract
We report the synthesis of 1,4-dicarbonyl compounds and substituted alkenes (Mizoroki–Heck type coupling) starting from secondary and tertiary alkyl halides and vinyl acetate or styrene derivatives using visible-light photocatalysis.
Topics & Concepts
PhotocatalysisHalideAlkylChemistryHeck reactionStyreneVisible spectrumOrganic chemistryPhotochemistryCombinatorial chemistryCatalysisMaterials scienceArylCopolymerPolymerOptoelectronicsRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization Methods