Fluorinated linkers enable the synthesis of flexible MOFs with 1D alkaline earth SBUs and a temperature-induced phase transition
Sean S. Sebastian, Finn P. Dicke, Uwe Ruschewitz
Abstract
] (EA(II) = Ca, Sr) utilizing a fluorinated derivative of the BTB-linker (perfluorination of the inner benzene ring) with a unique topology, crystalline sponge behaviour and a low temperature induced phase transition.
Topics & Concepts
SBusAlkaline earth metalPhase transitionPhase (matter)Phase changeMaterials scienceEarth (classical element)NanotechnologyChemistryAlkali metalEngineering physicsCondensed matter physicsOrganic chemistryPhysicsMetal-organic frameworkMathematical physicsAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research