Photocatalytic 1,2-oxo-alkylation reaction of styrenes with diazoacetates
Fang Li, Siqi Zhu, René M. Koenigs
Abstract
We report on the photocatalytic 1,2-difunctionalization reaction of styrenes with acceptor-only diazoalkanes.
Topics & Concepts
CyclopropaneAlkylationReactivity (psychology)CarbeneDABCOEthyl diazoacetateChemistryYield (engineering)PhotocatalysisCatalysisPhotochemistryMedicinal chemistryOrganic chemistryCyclopropanationMaterials scienceRing (chemistry)MedicinePathologyMetallurgyAlternative medicineCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsSynthesis and Catalytic Reactions