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Multifunctional Superelastic Graphene-Based Thermoelectric Sponges for Wearable and Thermal Management Devices

Ding Zhang, Yin Mao, Peijia Bai, Qi Li, Wen He, Heng Cui, Fei Ye, Chenxi Li, Rujun Ma, Yongsheng Chen

2022Nano Letters69 citationsDOI

Abstract

Power generation through harvesting human thermal energy provides an ideal strategy for self-powered wearable design. However, existing thermoelectric fibers, films, and blocks have small power generation capacity and poor flexibility, which hinders the development of self-powered wearable electronics. Here, we report a multifunctional superelastic graphene-based thermoelectric (TE) sponge for wearable electronics and thermal management. The sponge has a high Seebeck coefficient of 49.2 μV/K and a large compressive strain of 98%. After 10 000 cyclic compressions at 30% strain, the sponge shows excellent mechanical and TE stability. A wearable sponge array TE device was designed to drive medical equipment for monitoring physiological signals by harvesting human thermal energy. Furthermore, a 4 × 4 array TE device placed on the surface of a normal working Central Processing Unit (CPU) can generate a stable voltage and reduce the CPU temperature by 8 K, providing a feasible strategy for simultaneous power generation and thermal management.

Topics & Concepts

Materials scienceElectronicsWearable computerThermoelectric effectWearable technologyEnergy harvestingGrapheneFlexible electronicsThermoelectric generatorThermoelectric materialsNanotechnologyOptoelectronicsElectrical engineeringPower (physics)Thermal conductivityComputer scienceComposite materialEmbedded systemEngineeringPhysicsQuantum mechanicsThermodynamicsAdvanced Thermoelectric Materials and DevicesAdvanced Sensor and Energy Harvesting MaterialsSupercapacitor Materials and Fabrication