Tethered photocatalyst-directed palladium-catalysed C–H allenylation of <i>N</i>-aryl tetrahydroisoquinolines
Mingfeng Li, Xiu Li Chia, Ye Zhu
Abstract
We realised a new control strategy for Pd-catalysed C–H allenylation through engineering covalently tethered transition metal–photocatalysts.
Topics & Concepts
RegioselectivityArylChemistryPalladiumCombinatorial chemistryCovalent bondPhosphinePhotoredox catalysisCatalysisPhotocatalysisOrganic chemistryAlkylCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques