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First-principles investigation of inorganic antiperovskite A<sub>3</sub>SbAs (A = Ba, Sr, and Ca): insights into thermoelectric and optoelectronic potential

Lakhdar Benahmedi, Besbes Anissa, Djelti Radouan, Sidahmed Bendehiba, Aissani Ali

2025New Journal of Chemistry12 citationsDOI

Abstract

This study investigates the physical, mechanical, and thermal properties of A₃SbAs (A = Ba, Sr, Ca) antiperovskites using DFT, revealing stable cubic structures, direct band gaps, and strong potential for sustainable energy technologies.

Topics & Concepts

ChemistryAntiperovskiteThermoelectric effectOptoelectronicsEngineering physicsThermodynamicsNitrideOrganic chemistryLayer (electronics)EngineeringPhysicsThermal Expansion and Ionic ConductivityPerovskite Materials and ApplicationsAdvanced Thermoelectric Materials and Devices
First-principles investigation of inorganic antiperovskite A<sub>3</sub>SbAs (A = Ba, Sr, and Ca): insights into thermoelectric and optoelectronic potential | Litcius