Photoactive electron donor–acceptor complex platform for Ni-mediated C(sp<sup>3</sup>)–C(sp<sup>2</sup>) bond formation
Lisa Marie Kammer, Shorouk O. Badir, Ren‐Ming Hu, Gary A. Molander
Abstract
)-centered radical architectures (including primary, secondary, stabilized benzylic, α-oxy, and α-amino systems) with (hetero)aryl bromides has been accomplished. The protocol proceeds under mild reaction conditions in the presence of sensitive functional groups and pharmaceutically relevant cores.
Topics & Concepts
StoichiometryAcceptorElectron acceptorChemistryElectron donorMetalElectronCatalysisPhotochemistryCrystallographyPhysical chemistryPhysicsOrganic chemistryNuclear physicsCondensed matter physicsCatalytic C–H Functionalization MethodsCO2 Reduction Techniques and CatalystsRadical Photochemical Reactions