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Incorporating Gadolinium Oxide (Gd<sub>2</sub>O<sub>3</sub>) as a Rare Earth Metal Oxide in Carbon Nanofiber Skeleton for Supercapacitor Application

Hamide Aydın, Burcu Üstün, Ü. Kurtan, Ayşe Aslan, Selcan Karakuş

2024ChemElectroChem34 citationsDOIOpen Access PDF

Abstract

Abstract In this study, we synthesized gadolinium oxide nanoparticles (Gd 2 O 3 NPs) incorporated heteroatom‐doped microporous carbon nanofibers (CNF) to serve as electrode materials for enhancing supercapacitive energy storage. Our primary focus is on elucidating the impact of these hybrid electrode materials on key supercapacitor performance properties such as specific capacitance, specific energy, and specific power. To comprehensively assess the structural and chemical attributes of Gd 2 O 3 NPs‐incorporated heteroatom‐doped microporous CNFs (CNF/Gd 2 O 3 ) we employed an array of advanced characterization techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy (RAMAN), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). Our research has yielded impressive results, demonstrating a significant increase in supercapacitive performance. Specifically, the CNF/Gd 2 O 3 ‐1 symmetric supercapacitor cell (SSC) has demonstrated a good specific capacitance of 162.3 F/g and a high specific energy of 8.12 Wh/kg at a specific power of 300 W/kg. These findings could be a new pathway to prepare composite electrodes for use in energy storage applications and promote further development for other rare‐earth nanostructures.

Topics & Concepts

SupercapacitorMaterials scienceX-ray photoelectron spectroscopyNanofiberMicroporous materialRaman spectroscopyOxideNanotechnologyCarbon nanofiberChemical engineeringScanning electron microscopeElectrodeCapacitanceCarbon nanotubeComposite materialChemistryOpticsMetallurgyPhysical chemistryEngineeringPhysicsSupercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical ApplicationsAdvancements in Battery Materials
Incorporating Gadolinium Oxide (Gd<sub>2</sub>O<sub>3</sub>) as a Rare Earth Metal Oxide in Carbon Nanofiber Skeleton for Supercapacitor Application | Litcius