Construction of helical structures with planar chiral [2.2]paracyclophane: fusing helical and planar chiralities
Motoki Tsuchiya, Hazuki Maeda, Ryo Inoue, Yasuhiro Morisaki
Abstract
Planar chiral pseudo- meta -disubstituted [2.2]paracyclophane was optically resolved on the sub-gram-scale by a diastereomer method. One-handed helical molecules were prepared using the enantiopure [2.2]paracyclophane.
Topics & Concepts
PlanarCrystallographyPlanar chiralityMaterials scienceStereochemistryChemistryEnantioselective synthesisComputer scienceOrganic chemistryComputer graphics (images)CatalysisSynthesis and Properties of Aromatic CompoundsDNA and Nucleic Acid ChemistrySupramolecular Self-Assembly in Materials