The solvothermal synthesis and characterization of quaternary arsenic chalcogenides CsTMAsQ<sub>3</sub> (TM = Hg, Cd; Q = S, Se) using Cs<sup>+</sup> as a structure directing agent: from 1D anionic chains to 2D anionic layers
Xinyu Tian, Cui-Xia Du, Zhaori Getu, Muge Shele, Yong‐Sheng Bao, Menghe Baiyin
Abstract
Presented is a method involving TM–As–Q (TM = Hg, Cd; Q = S, Se) quaternary arsenic chalcogenides and different mixed solvents which has been used to synthesize four new quaternary chalcogenide compounds.
Topics & Concepts
IsostructuralChemistryChalcogenideSolvothermal synthesisArsenicCrystallographyChalcogenSolventRing (chemistry)OctahedronStereochemistryInorganic chemistryCrystal structureOrganic chemistryCrystal Structures and PropertiesChalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallography