Potassium Ion–Assisted Self–Assembled MXene-K-CNT Composite as High–Quality Sulfur–Loaded Hosts for Lithium–Sulfur Batteries
Yaoying Li, Ruoxi Yang, Jiawei Xie, Jia Li, Haifu Huang, Xianqing Liang, Dan Huang, Zhiqiang Lan, Haizhen Liu, Guangxu Li, Shuaikai Xu, Jin Guo, Wenzheng Zhou
Abstract
We successfully synthesized hybrid MXene-K-CNT composites composed of alkalized two-dimensional (2D) metal carbide and carbon nanotubes (CNTs), which were employed as host materials for lithium–sulfur (Li–S) battery cathodes. The unique three-dimensional (3D) intercalated structure through electrostatic interactions by K + ions in conjunction with the scaffolding effect provided by CNTs effectively inhibited the self-stacking of MXene nanosheets, resulting in an enhanced specific surface area (SSA) and ion transport capability. Moreover, the addition of CNTs and in situ –grown TiO 2 considerably improved the conductivity of the cathode material. K + ion etching created a more hierarchical porous structure in MXene, which further enhanced the SSA. The 3D framework effectively confined S embedded between nanosheet layers and suppressed volume changes of the cathode composite during charging/discharging processes. This combination of CNTs and alkalized nanosheets functioned as a physical and chemical dual adsorption system for lithium polysulfides (LiPSs). When subjected to a high current at 1.0C, [email protected] with S-loaded of 1.2 mg cm –2 had an initial capacity of 919.6 mAh g –1 and capacity decay rate of merely 0.052% per cycle after 1000 cycles. Moreover, [email protected] maintained good cycling stability even at a high current of up to 5.0C. These impressive results highlight the potential of alkalized 2D MXene nanosheets intercalated with CNTs as highly promising cathode materials for Li–S batteries. The study findings also have prospects for the development of next-generation Li–S batteries with high energy density and prolonged lifespans.