Surface Modified CoCrFeNiMo High Entropy Alloys for Oxygen Evolution Reaction in Alkaline Seawater
Zhibin Chen, Kang Huang, Tianyi Zhang, Jiuyang Xia, Junsheng Wu, Zequn Zhang, Bowei Zhang
Abstract
Electrolysis of seawater is a promising technique to desalinate seawater and produce high-purity hydrogen production for freshwater and renewable energy, respectively. For the application of seawater electrolysis technique on a large scale, simplicity of manufacture method, repeatability of catalyst products, and stable product quality is generally required in the industry. In this work, a facile, one-step, and metal salt-free fabrication method was developed for the seawater-oxygen-evolution-active catalysts composed of CoCrFeNiMo layered double hydroxide array self-supported on CoCrFeNiMo high entropy alloy substrate. The obtained catalysts show improved performance for oxygen evolution reaction in alkaline artificial seawater solution. The best-performing sample delivered the current densities of 10, 50, and 100 mA cm−2 at low overpotentials of 260.1, 294.3, and 308.4 mV, respectively. In addition, high stability is also achieved since no degradation was observed over the chronoamperometry test of 24 h at the overpotential corresponding to 100 mA cm−2. Furthermore, a failure mechanism OER activity of multi-element LDHs catalysts was put forward in order to enhance catalytic performance and design catalysts with long-term durability.