Novel Chiral <scp>Ligands‐Enabled Transition‐Metal‐Catalyzed</scp> Asymmetric C—H Borylation
Miao Zhan, Peidong Song, Jiao Jiao, Pengfei Li
Abstract
Although C—H borylation has been recognized as an efficient approach to organoboron compounds, the asymmetric variants have emerged only very recently. These results pointed out that the development of novel chiral ligands was pivotal to the success of asymmetric C—H borylation. Herein, a brief summary and comments on the key progresses are presented.
Topics & Concepts
BorylationChemistryOrganoboron compoundsEnantioselective synthesisCatalysisCombinatorial chemistryStereochemistryTransition metalOrganic chemistryArylAlkylCatalytic C–H Functionalization MethodsOrganoboron and organosilicon chemistryCatalytic Cross-Coupling Reactions