Textile Dye Removal by Acacia dealbata Link. Pollen Adsorption Combined with UV-A/NTA/Fenton Process
Ana R. Teixeira, Nuno Jorge, José R. Fernandes, Marco S. Lucas, José A. Peres
Abstract
Abstract The decolourization of an aqueous solution of the textile dye Acid Red 88 (AR88) and the control of the invasive plant species Acacia dealbata Link . (ADL) were addressed in this work. The aims of the study were (1) characterization of the ADL pollen, (2) application of the pollen powder in adsorption processes, (3) selection of the best operational conditions for nitriloacetic acid (NTA)-UV-A-Fenton process and (4) assess the efficiency of the combined treatment adsorption and NTA-UV-A-Fenton in AR88 decolourization. In a first step, ADL pollen was used as a AR88 bioadsorbent. Fourier-transform infrared spectroscopy (FTIR) analysis were performed and revealed the presence of proteins, fatty acids, carbohydrates and lignin in the pollen. Afterwards, trough scanning electron microscopy (SEM), it was possible to verify that ADL pollen has several empty spaces that can be used for dye adsorption. Biosorption results showed higher adsorption of AR88 with application of pH 3.0 and [pollen] = 3.0 g/L with 18.8 mg/g of dye adsorbed. The best fitting was observed with Langmuir, SIPS and Jovanovic isotherms (0.993, 0.996 and 0.994, respectively). To complement the biosorption, a UV-A-Fenton process was applied, and results showed a higher AR88 removal with (NTA) addition. Higher irradiance power favored the oxidation process with high Ф photodegradation value and low Electric Energy per Order ( $$E_{\text{EO}}$$ <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msub> <mml:mi>E</mml:mi> <mml:mtext>EO</mml:mtext> </mml:msub> </mml:math> ) and Specific Applied Energy ( $$E_{\text{SAE}}$$ <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msub> <mml:mi>E</mml:mi> <mml:mtext>SAE</mml:mtext> </mml:msub> </mml:math> ). The combination of biosorption with NTA-UV-A-Fenton was the most efficient system with an AR88 decolourization of 98.5% and a total organic carbon (TOC) removal of 83.5%. Graphical Abstract