A reagent for heteroatom borylation, including iron mediated reductive deoxygenation of nitrate yielding a dinitrosyl complex
Daniel M. Beagan, Veronica Carta, Kenneth G. Caulton
Abstract
is the quantitative fate of the removed oxo groups. With borylation of both nitrogen heterocycles and doubly deoxygenating two nitrates coordinated to a single metal center, broad spectrum methodology is demonstrated.
Topics & Concepts
DeoxygenationBorylationHeteroatomReagentChemistryNitrateCombinatorial chemistryInorganic chemistryPhotochemistryOrganic chemistryCatalysisRing (chemistry)ArylAlkylOrganoboron and organosilicon chemistryMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions