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Visualizing the Geometry of Hydrogen Dimers

Arnab Khan, T. Jahnke, S. Zeller, Florian Trinter, M. S. Schöffler, Lothar Schmidt, R. Dörner, M. Kunitski

2020The Journal of Physical Chemistry Letters23 citationsDOI

Abstract

] obtained via femtosecond laser-induced Coulomb explosion imaging. Our results indicate that hydrogen dimers are not restricted to a particular geometry but rather occur as a mixture of all possible configurations. The measured intermolecular distance distributions were used to deduce the isotropic intermolecular potential as well as the binding energies of the dimers.

Topics & Concepts

Intermolecular forceDimerCoulomb explosionIsotropyFemtosecondHydrogenBinding energySurface (topology)Atomic physicsMolecular physicsQuantumPotential energy surfacePhysicsChemistryChemical physicsGeometryLaserMoleculeQuantum mechanicsNuclear magnetic resonanceMathematicsIonizationIonLaser-Matter Interactions and ApplicationsAtomic and Molecular PhysicsMass Spectrometry Techniques and Applications
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