Polymorphism and Mechanochromism in 2-Phenylbenzothiazole Cyclometalated Pt<sup>II</sup> Complexes with Chelating N<sup>∧</sup>O Ligands
David Gómez de Segura, Elena Lalinde, M. Teresa Moreno
Abstract
MM(L+L')CT in the oligomers. Noncovalent interaction (NCI) theoretical studies indicate that the π···π stacking among chelates also exerts a strong influence in the metal-metal-to-ligand charge transfer transition character.
Topics & Concepts
ChemistryStackingCrystallographySubstituentMonomerAcceptorPowder diffractionChelationTransition metalStereochemistryPolymerInorganic chemistryOrganic chemistryCatalysisPhysicsCondensed matter physicsLuminescence and Fluorescent MaterialsOrganic Light-Emitting Diodes ResearchPorphyrin and Phthalocyanine Chemistry