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B-site high valence cation co-doping boosts fast oxygen kinetics in a cobalt-free perovskite air electrode for reversible solid oxide cells

Chenshuo Yuan, Dongwang Feng, Hui Ye, Pengkai Shan, Lin Ge, Han Chen, Yifeng Zheng, Sheng Cui

2025Journal of Materials Chemistry A7 citationsDOI

Abstract

A B-site co-doping strategy by incorporating high valence Nb 5+ and Ta 5+ into a cobalt-free Bi 0.5 Sr 0.5 FeO 3− δ (BSF) air electrode to synergistically optimize the oxygen transport capacity and surface reactivity for RSOCs.

Topics & Concepts

CobaltValence (chemistry)Perovskite (structure)ElectrodeDopingOxideKineticsMaterials scienceCobalt oxideOxygenInorganic chemistryChemistryOptoelectronicsCrystallographyPhysical chemistryMetallurgyPhysicsQuantum mechanicsOrganic chemistryAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of OxidesMagnetic and transport properties of perovskites and related materials
B-site high valence cation co-doping boosts fast oxygen kinetics in a cobalt-free perovskite air electrode for reversible solid oxide cells | Litcius