Boosting H<sub>2</sub> Production from a BiVO<sub>4</sub> Photoelectrochemical Biomass Fuel Cell by the Construction of a Bridge for Charge and Energy Transfer
Zhaoqi Wang, Zhaoqi Wang, Yuhao Guo, Mu Liu, Xiaolei Liu, Haipeng Zhang, Weiyi Jiang, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Hefeng Cheng, Ying Dai, Zeyan Wang, Zeyan Wang, Baibiao Huang
Abstract
Abstract Utilizing a photoelectrochemical (PEC) fuel cell to replace difficult water oxidation with facile oxidation of organic wastes is regarded as an effective method to improve the H 2 production efficiency. However, in most reported PEC fuel cells, their PEC activities are still low and the energy in organic fuels cannot be effectively utilized. Here, a unique BiVO 4 PEC fuel cell is successfully developed by utilizing the low‐cost biomass, tartaric acid, as an organic fuel. Thanks to the strong complexation between BiVO 4 and tartaric acid, a bridge for the charge and energy transfer is successfully constructed, which not only improves the photoelectric conversion efficiency of BiVO 4 , but also effectively converts the chemical energy of biomass into H 2 . Remarkably, under AM1.5G illumination, the optimal nanoporous BiVO 4 photoanode exhibits a high current density of 13.54 mA cm −2 at 1.23 V vs reversible hydrogen electrode (RHE) for H 2 production, which is higher than that of previously reported PEC water splitting systems or PEC fuel cell systems. This work opens a new path for solving the low PEC H 2 production efficiency and provides a new idea for improving the performances and energy conversion efficiency in traditional PEC fuel cells.