Ruthenium-Catalyzed Asymmetric <i>N</i>-Acyl Nitrene Transfer Reaction: Imidation of Sulfide
Masaki Yoshitake, Hiroki Hayashi, Tatsuya Uchida
Abstract
-acyl nitrene intermediates without any activation via heating or UV irradiation, or transfer generating nitrene intermediates to the sulfur atom of sulfides with good to excellent enantioselectivities (≤98% ee) without diazene and isocyanate contamination.
Topics & Concepts
NitreneChemistryRutheniumCatalysisSulfideTransfer (computing)Combinatorial chemistryPhotochemistryOrganic chemistryMedicinal chemistryParallel computingComputer scienceSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis