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A [(M<sub>2</sub>)<sub>6</sub>L<sub>8</sub>] metal–organic polyhedron with high CO<sub>2</sub> uptake and efficient chemical conversion of CO<sub>2</sub> under ambient conditions

Lihua Liu, Lihua Liu, Lin Liu, Lin Liu, Hao-Ran Chi, Chen-Ning Li, Zheng‐Bo Han

2022Chemical Communications24 citationsDOI

Abstract

A new rhombic dodecahedron Cu–MOP with high absorption of CO 2 has been successfully synthesized, and it exhibits excellent performance in chemical fixation of CO 2 into cyclic carbonates under ambient conditions.

Topics & Concepts

PolyhedronMetalCatalysisTransition metalChemistryMaterials scienceCrystallographyOrganic chemistryGeometryMathematicsMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications
A [(M<sub>2</sub>)<sub>6</sub>L<sub>8</sub>] metal–organic polyhedron with high CO<sub>2</sub> uptake and efficient chemical conversion of CO<sub>2</sub> under ambient conditions | Litcius