Enhanced stability and ultrahigh proton conductivity of hydrogen-bonded organic frameworks
Qianqian Yang, Xinyu Li, Changsong Xie, Zhen Wang, Zhihui Kong, Jianjian Yang, Zixi Kang, Rongming Wang, Daofeng Sun
Abstract
A highly stable HOF-based composite (HDSD-1@Tp) was obtained by in situ reaction with HDSD-1. The introduction of NH 4 + optimizes its proton conduction pathways, making HDSD-1@Tp-NH 3 possess a high proton conductivity of 3.8 × 10 −1 S cm −1 .
Topics & Concepts
ProtonMaterials scienceConductivityThermal conductionHydrogenComposite numberChemical engineeringAnalytical Chemistry (journal)Physical chemistryComposite materialOrganic chemistryChemistryNuclear physicsEngineeringPhysicsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsFuel Cells and Related Materials