N-doped nonalternant aromatic belt <i>via</i> a six-fold annulative double N-arylation
Hiroki Sato, Rie Suizu, Tomoki Kato, Akiko Yagi, Yasutomo Segawa, Kunio Awaga, Kenichiro Itami
Abstract
-methoxyaniline moieties, was studied, and a stable dication species was successfully identified by X-ray crystallography. The present study not only shows the unique structure and properties of the N-doped nonalternant aromatic belt but also expands the scope of accessibility of synthetically difficult belt molecules by the conventional intramolecular contraction pathway.
Topics & Concepts
ChemistryFold (higher-order function)StereochemistryCrystallographyComputer scienceProgramming languageSynthesis and Properties of Aromatic CompoundsOrganoboron and organosilicon chemistryLuminescence and Fluorescent Materials