Palladium-catalysed diastereodivergent inverse-electron-demand oxa-Diels–Alder reactions of <i>in situ</i> formed cyclopentadienones <i>via</i> ligand-control
Xing‐Xing Yang, Xingliang Zhao, Qin Ouyang, Wei Du, Ying‐Chun Chen
Abstract
Pd(0)-Catalysed asymmetric inverse-electron-demand oxa-Diels–Alder reactions between the carbonates of 4-hydroxy-2-cyclopentenones and several kinds of α,β-unsaturated carbonyls are reported.
Topics & Concepts
ChemistryLigand (biochemistry)Diels–Alder reactionPalladiumMedicinal chemistryInverseIn situCatalysisOrganic chemistryReceptorMathematicsGeometryBiochemistryCyclopropane Reaction MechanismsAsymmetric Synthesis and CatalysisAsymmetric Hydrogenation and Catalysis