Realization of Stacked-Ring Aromaticity in a Water-Soluble Micellar Capsule
Siyu Liu, Natsuki Kishida, Jinseok Kim, Norihito Fukui, Rie Haruki, Y. Niwa, Reiji Kumai, Dongho Kim, Michito Yoshizawa, Hiroshi Shinokubo
Abstract
-isopropyl NC, which does not exhibit π-stacking even in a concentrated solution or the crystalline phase, adopted π-stacking with stacked-ring aromaticity in the supramolecular micellar capsule.
Topics & Concepts
AromaticityStackingChemistryAntiaromaticitySupramolecular chemistryRing (chemistry)Bathochromic shiftCrystallographyChemical physicsCrystal structureOrganic chemistryMoleculePhysicsQuantum mechanicsFluorescenceSynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in MaterialsSupramolecular Chemistry and Complexes