Oxidative dehydrogenation of cyclohexene on atomically precise subnanometer Cu<sub>4−<i>n</i></sub>Pd<sub><i>n</i></sub> (0 ≤ <i>n</i> ≤ 4) tetramer clusters: the effect of cluster composition and support on performance
Juraj Jašík, Stanislav Valtera, Mykhailo Vaidulych, Muntaseer Bunian, Lei Yu, Avik Halder, Hana Tarábková, Martin Jindra, Ladislav Kavan, Otakar Frank, Stephan Bartling, Štefan Vajda
Abstract
High fidelity selectivity tuning of the oxidative dehydrogenation of cyclohexene was achieved through the control of the atomic composition of CuPd clusters and their interactions with the support.
Topics & Concepts
DehydrogenationTetramerCluster (spacecraft)CyclohexeneCrystallographyChemistryChemical physicsOxidative phosphorylationMaterials scienceComputational chemistryNanotechnologyCatalysisOrganic chemistryComputer scienceProgramming languageBiochemistryEnzymeCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsMachine Learning in Materials Science