The effect of the position of cross-linkers on the structure and microenvironment of PPh<sub>3</sub> moiety in porous organic polymers
Guangjun Ji, Cunyao Li, Dong Xiao, Guoqing Wang, Zhao Sun, Miao Jiang, Guangjin Hou, Li Yan, Yunjie Ding
Abstract
An effective and feasible strategy to precisely regulate the framework of PPh<sub>3</sub> based porous organic ligands (POLs) and the corresponding coordination microenvironment surrounding Rh was put forward by changing the position of cross-linkers.
Topics & Concepts
MoietyPolymerPorosityChemistryPosition (finance)NanotechnologyMaterials sciencePolymer chemistryCombinatorial chemistryChemical engineeringStereochemistryOrganic chemistryBusinessEngineeringFinanceMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMembrane Separation and Gas Transport