Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar <i>cis</i> -[Zr <sub>6</sub> F <sub>34</sub> ] <sup>10−</sup> clusters
Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo
Abstract
dodecahedra are the dominant contributors to the large band gap (7.89 eV, cal.) and SHG response simultaneously. Such systematic work highlights that Zr-based fluorides afford a new paradigm for the development of efficient NLO materials with a short UV cutoff edge.
Topics & Concepts
UltravioletWavelengthFluorideNonlinear opticalPolarCutoffNonlinear systemEnhanced Data Rates for GSM EvolutionNonlinear opticsOptical materialsPhysicsMaterials scienceOpticsAnalytical Chemistry (journal)ChemistryOptoelectronicsMolecular physicsInorganic chemistryTelecommunicationsOrganic chemistryComputer scienceAstronomyQuantum mechanicsCrystal Structures and PropertiesInorganic Fluorides and Related CompoundsInorganic Chemistry and Materials