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Electrocatalytic Pathways to the Formation of C–N Bonds

Dimitra Anastasiadou, Marta C. Figueiredo

2024ACS Catalysis43 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide The electrochemical synthesis of organonitrogen compounds characterized by the presence of C–N bonds has emerged in the past few years as an appealing alternative for the industrial-scale production of these compounds. Given their high industrial and societal importance, finding sustainable production methods is crucial. However, their production depends on the Haber Bosch process, which has a substantial environmental impact. In response to these challenges and recognizing the scientific challenge of making C–N bonds on an electrochemical interface, there is a notable surge in interest from the scientific community. This review summarizes some of the latest contributions to electrochemical C–N bond formation (urea, amides, and amines) concerning catalyst development and reaction mechanism elucidation.

Topics & Concepts

ElectrocatalystChemistryCatalysisStereochemistryElectrochemistryOrganic chemistryElectrodePhysical chemistryAmmonia Synthesis and Nitrogen ReductionCO2 Reduction Techniques and CatalystsElectrocatalysts for Energy Conversion
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