Eight-electron copper-hydride nanoclusters: synthesis, structure, alloying chemistry and photoluminescence
Jing Sun, Jiahe Liu, Hai‐Feng Su, Simin Li, Xiongkai Tang, Zhen‐Lang Xie, Zhen Xu, Wenya Jiang, Jianyu Wei, Xuekun Gong, Ayisha He, Song Wang, De‐en Jiang, Nanfeng Zheng, Hui Shen
Abstract
clusters, which exhibit significant structural differences from the parent cluster. Both the homo and alloy clusters display dual-emission properties at 298 K, with the clusters additionally showcasing triple or even quadruple emission at 77 K. This work is anticipated to stimulate research interest in hydride-containing metal nanoclusters, focusing not only on compositional tailoring and structural engineering, but also on electronic structure details and potential applications.
Topics & Concepts
NanoclustersPhotoluminescenceCopperHydrideChemistryElectronInorganic chemistryMaterials scienceNanotechnologyMetallurgyPhysicsMetalOptoelectronicsNuclear physicsNanocluster Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Chemistry and Materials