Polarisation effects on the H-bond acceptor properties of secondary amides
Fergal E. Hanna, Alexander J. Root, Christopher A. Hunter
Abstract
measured for the secondary amide H-bond donor and H-bond acceptor is identical, which implies that polarisation of an amide mediates the interaction between an external donor or acceptor in a reciprocal manner.
Topics & Concepts
ChemistryIntramolecular forceCooperativityAcceptorPyridineAmideIntermolecular forceHydrogen bondCrystallographyElectron acceptorMoleculePhotochemistryStereochemistryMedicinal chemistryOrganic chemistryBiochemistryCondensed matter physicsPhysicsMolecular spectroscopy and chiralityCrystallography and molecular interactionsAnalytical Chemistry and Chromatography