Pyrolysis of a metal–organic framework followed by <i>in situ</i> X-ray absorption spectroscopy, powder diffraction and pair distribution function analysis
Mads Folkjær, L. F. Lundegaard, Henrik S. Jeppesen, Melissa Marks, Mathias S. Hvid, Sara Frank, Giannantonio Cibin, Nina Lock
Abstract
O/Cu/carbon material with the desired metal/metal oxide composition. More importantly, our investigations serve as a benchmark study demonstrating that this methodology is generally applicable for studying the thermal decomposition of MOFs.
Topics & Concepts
X-ray absorption spectroscopyPowder diffractionPyrolysisIn situMetalPair distribution functionDiffractionAbsorption (acoustics)X-raySpectroscopyMaterials scienceAtomic absorption spectroscopyAbsorption spectroscopyMetal-organic frameworkAnalytical Chemistry (journal)X-ray crystallographyCrystallographyNuclear chemistryChemistryPhysical chemistryOrganic chemistryOpticsMetallurgyPhysicsComposite materialQuantum mechanicsAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsX-ray Diffraction in CrystallographyCrystallography and molecular interactions