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THz Gas Sensing Using Terahertz Time-Domain Spectroscopy with Ceramic Architecture

Keiji Komatsu, T. Iwamoto, Haruhiko Ito, Hidetoshi Saitoh

2022ACS Omega13 citationsDOIOpen Access PDF

Abstract

Ceramic architectures based on chemical vapor deposition (CVD) are used to create unique crystal structures, morphologies, and properties. This study proposed room-temperature THz gas sensing using terahertz time-domain spectroscopy (THz-TDS) with ceramic architectures. We synthesized ceramic films on porous glass. Zinc oxide films were created using atmospheric CVD and amorphous carbon nitride films using the dissociative excitation reaction of BrCN with metastable Ar atoms. The transmission method was used in THz-TDS. A stainless hand-made gas cell with a Si window was applied for THz gas sensing. We defined "phase delay" equals VOC sensing response amount of sensing materials at each duration. Ppm-order THz gas sensing was performed.

Topics & Concepts

Terahertz radiationMaterials scienceCeramicSpectroscopyChemical vapor depositionOptoelectronicsAmorphous solidAnalytical Chemistry (journal)Composite materialChemistryOrganic chemistryChromatographyPhysicsQuantum mechanicsAdvanced Chemical Sensor TechnologiesSpectroscopy and Laser ApplicationsGas Sensing Nanomaterials and Sensors
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