Photoinduced allylic defluorinative alkylation of trifluoromethyl alkenes with Katritzky salts under catalyst- and metal-free conditions
Zhu-Qian Cai, Rui Gu, Weili Si, Yubin Xiang, Jinwei Sun, Yan Jiao, Xuan Zhang
Abstract
A photoinduced method for the synthesis of gem -difluoroalkenes using trifluoromethyl alkenes and Katritzky salts under catalyst- and metal-free conditions is described.
Topics & Concepts
TrifluoromethylCatalysisChemistryAllylic rearrangementAlkylationMetalTsuji–Trost reactionOrganic chemistryPhotochemistryCombinatorial chemistryAlkylFluorine in Organic ChemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods