<i>In Situ</i> Studies of Arylboronic Acids/Esters and R<sub>3</sub>SiCF<sub>3</sub> Reagents: Kinetics, Speciation, and Dysfunction at the Carbanion–Ate Interface
Andrés García‐Domínguez, Andrew G. Leach, Guy C. Lloyd‐Jones
Abstract
attenuate the chain-branching, suppress autoacceleration, and lead to less rapid difluorocyclopropanation. The Account also highlights how a collaborative approach to experiment and computation enables mechanistic insight for control of processes.
Topics & Concepts
CarbanionKineticsIn situReagentGenetic algorithmChemistryInterface (matter)Materials scienceOrganic chemistryPhysicsMoleculeBiologyGibbs isothermQuantum mechanicsEvolutionary biologyFluorine in Organic ChemistryCoordination Chemistry and OrganometallicsMolecular Spectroscopy and Structure