Redox-controlled chalcogen-bonding at tellurium: impact on Lewis acidity and chloride anion transport properties

Abstract

Te, respectively. These new telluronium cations have been evaluated for their ability to complex and transport chloride anions across phospholipid bilayers. These studies show that, when compared to their neutral Te(ii) precursors, these Te(iv) cations display both higher Lewis acidity and transport activity. The positive attributes of these telluronium cations, which originate from a lowering of the tellurium-centered σ* orbitals and a deepening of the associated σ-holes, demonstrate that the redox state of the main group element provides a convenient handle over its chalcogen-bonding properties.

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