Optical Fiber SPR Sensor With Surface Ion Imprinting for Highly Sensitive and Highly Selective Ni<sup>2+</sup> Detection
Yao Ma, Wanlu Zheng, Yanan Zhang, Xuegang Li, Yong Zhao
Abstract
A reflective optical fiber nickel ion (Ni <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2+</sup> ) sensor based on surface plasmon resonance (SPR) and surface ion imprinting was proposed and demonstrated. The sensor is made of multimode optical fiber with a core diameter of 600 μm and coated with a gold film for an exciting SPR effect. To realize highly sensitive and highly selective detection of Ni <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2+</sup> , graphene oxide (GO) and Ni <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2+</sup> -imprinted Chitosan (IP-CS) are subsequently combined on the sensor surface. The GO can not only act as the intermediate binder between the Au film and the CS but also increase the sensitivity of the sensor. The Ni <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2+</sup> holes on the IP-CS can realize the specific capture of Ni <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2+</sup> . The experimental results show that the sensitivity of the sensor to Ni <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2+</sup> is 5.220 nm/[lg(mg/L)] with a limit of detection of 2.393×10 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-3</sup> mg/L, and the selectivity of the sensor is significantly improved after imprinting. Besides, the sensor has good stability and repeatability, and fast responsiveness.