Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
Álvaro García‐Romero, J.M. Martin-Alvarez, Daniel Miguel, Dominic S. Wright, Celedonio M. Álvarez, Raúl García‐Rodríguez
Abstract
are employed). This study therefore provides insight into the way in which the electronic effects of the bridgehead atom in these ligand systems can impact their supramolecular chemistry.
Topics & Concepts
ChemistryBismuthAntimonySupramolecular chemistryMain group elementCrystallographyCationic polymerizationCoordination complexMetalLigand (biochemistry)Crystal structureLewis acids and basesIonTripodal ligandTrisInorganic chemistryCrystal engineeringStereochemistryPolymer chemistryTransition metalOrganic chemistryBiochemistryCatalysisReceptorMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesMetal complexes synthesis and properties