Bulky 1,1′-bisphosphanoferrocenes and their coordination behaviour towards Cu(<scp>i</scp>)
Subhayan Dey, Dániel Buzsáki, Clemens Bruhn, Zsolt Kelemen, Rudolf Pietschnig
Abstract
-fixation reaction with terminal alkynes, and complexes with ligand 3 were found to be more efficient than those with 1. DFT calculations performed on compounds 1, 3 and their Cu(i) complexes were able to verify the trend of these catalytic reactions.
Topics & Concepts
Heteronuclear moleculeChemistryCatalysisLigand (biochemistry)Cyclic voltammetryCrystallographyMedicinal chemistryNuclear magnetic resonance spectroscopyStereochemistryPhysical chemistryOrganic chemistryElectrochemistryElectrodeBiochemistryReceptorOrganometallic Complex Synthesis and CatalysisFerrocene Chemistry and ApplicationsSynthesis and characterization of novel inorganic/organometallic compounds