Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides
Marc Magre, Josep Cornellà
Abstract
into Bi-C bonds, leading to a structurally unique O-bound bismuth sulfinate complex. The catalytic protocol affords excellent yields for a wide range of aryl and heteroaryl boronic acids, displaying a wide functional group tolerance.
Topics & Concepts
ChemistryArylSulfonylCatalysisBismuthSulfoneCatalytic cycleCombinatorial chemistryRedoxOxidation stateGroup 2 organometallic chemistryLigand (biochemistry)Organic chemistryMoleculeAlkylReceptorBiochemistrySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic Cross-Coupling Reactions